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Research draft

cinnabar

vr.tr.cinnabar · PHY.MAT

Enable an agent to identify cinnabar, assess the composition and condition of a specimen or material lot, and determine which examinations, uses and handling actions are justified.

Thing Registry Physical world and living systems

Research draft, second pass

A second pass drafted this model: the structure a model of this thing needs, and what is known about it in the world. The line under this one says how the second half was obtained - researched against sources, or recalled without web access, in which case nothing here was read anywhere and every claim is a lead to verify. Unreviewed either way.

recalled by Codex without web access - no source was read

Researched by: Codex

Purpose and description

Enable an agent to identify cinnabar, assess the composition and condition of a specimen or material lot, and determine which examinations, uses and handling actions are justified.

Cinnabar is the naturally occurring, red, trigonal crystalline form of mercury(II) sulfide (HgS), a mineral that is the principal ore of mercury.

It can be Evaluate whether identification evidence supports cinnabar, a mixed material or an unresolved red substance.; Select a minimally disruptive examination capable of resolving the actual identity question.; Assess a specimen or lot against a stated phase-purity, provenance or research requirement.; Track condition changes and trigger analysis when discolouration or shedding appears.; Determine whether proposed handling, sampling or processing has adequate material-specific controls and authorization.; Link cinnabar content to its host specimen, product or waste record..

Distinguishing features

Require evidence for the α-HgS crystal phase; detecting mercury and sulfur alone does not establish cinnabar. Reference identity: [CSIRO cinnabar record](https://spectroscopy.csiro.au/material/Cinnabar).

Use the combination of red coloration, scarlet streak, Mohs hardness around 2-2.5 and measured density near 8.18 g/cm³ as supporting evidence, with matrix and sampling effects recorded. These are reference properties, not requirements for destructive testing: [Handbook of Mineralogy](https://handbookofmineralogy.org/pdfs/cinnabar.pdf).

Distinguish red lookalikes through phase-sensitive analysis; a red appearance or pigment trade name is insufficient.

Separate natural provenance from synthetic origin; matching phase identity does not establish geological origin.

Distinguish a cinnabar-bearing rock or coating from a substantially single-phase cinnabar sample by recording the host and phase fraction.

Scope

+ Mineral and phase identification, including evidence and uncertainty

+ HgS composition, cinnabar phase fraction, impurities and associated minerals

+ Natural or synthetic origin and specimen or lot provenance

+ Physical form, diagnostic properties and condition changes

+ Evidence governing examination, storage, use and disposal

- Mercury metal and mercury compounds other than the cinnabar phase

- Metacinnabar and other HgS phases as independent materials

- Whole ore deposits, mining operations and mercury extraction processes

- Paint, lacquer, jewellery and other products containing or merely named after cinnabar

- Clinical diagnosis and treatment of mercury exposure

Characteristics

Phase identification
Confirmed α-HgS; probable cinnabar; mixed HgS phases; unresolved; method and reference Determines whether the registered identity applies.
Cinnabar phase fraction
Mass %, with analytical method, uncertainty and detection limits Separates cinnabar content from total mercury content and bulk material identity.
Elemental composition and impurities
Hg and S in mass % or atomic ratio; impurities in mg/kg or mass % Supports composition assessment without assuming that every detected mercury atom belongs to cinnabar.
Associated phases and host
Identified minerals, substrate or binder; estimated abundance; analytical evidence Explains properties and restrictions caused by material accompanying cinnabar.
Origin
Natural; synthetic; mixed; unknown Keeps material identity separate from provenance and authenticity claims.
Physical form and particle size
Crystal, massive aggregate, coating or powder; dimensions in mm; particle distribution in µm Influences sampling, containment and the consequences of disturbance.
Diagnostic physical observations
Density in g/cm³; Mohs hardness; colour and streak descriptions; method and sample condition Provides corroborating identity evidence while exposing measurements distorted by the host material.
Surface and aggregate condition
Intact; friable; shedding; discoloured; coated; altered; unknown Determines whether condition has changed enough to require reassessment.
Thermal behaviour evidence
Event temperature in °C or K; pressure; atmosphere; event type; method Prevents a phase transition, decomposition or volatilisation event from being recorded indiscriminately as a melting or boiling point.
Chemical identifier mapping
Verified CAS number, PubChem CID and EC number; issuing record; scope and verification date Shows whether an identifier denotes cinnabar specifically, mercury sulfide generally or a commercial preparation.
Applicable hazard and exposure basis
Source-backed classification and exposure limits, including jurisdiction, date, mercury species, route and units Supports decisions without transferring classifications or limits between unlike mercury materials.

Where this came from

wikidata · CC0 1.0

Also registered as vr.tr.cinnabar

Drafted structure

Bundle to layer to finding to question, as the second pass will find it: 6 bundles · 11 layers · 18 findings · 30 questions.

Cinnabar identity Establish whether the material belongs to the cinnabar entry.

Colour, chemical composition and trade terminology can each suggest cinnabar without proving its phase identity.

Phase evidence

Connect the identity claim to interpretable analytical observations.

α-HgS identification

Record the evidence and confidence supporting a cinnabar phase assignment.

  1. Which diffraction or spectroscopic observations support α-HgS, and which reference was used? measurement
  2. Does the evidence distinguish cinnabar from other HgS phases and mixtures? boundary

Name and entity boundaries

Separate the mineral phase from names applied to commercial or composite objects.

Cinnabar name resolution

Resolve what a label such as cinnabar or vermilion identifies in this record.

  1. Does the name denote verified cinnabar, a pigment preparation, a colour or an untested seller claim? definition
  2. Is this record about cinnabar itself or its occurrence within a separately modelled object? boundary
Composition and grade Describe how much cinnabar is present and what accompanies it.

A mercury assay alone cannot establish cinnabar purity or suitability for a particular use.

Phase and element abundance

Keep elemental concentration distinct from mineral abundance.

Assay interpretation

Capture phase fraction, elemental results and the assumptions connecting them.

  1. What cinnabar mass fraction was measured, by which method and with what uncertainty? measurement
  2. Was cinnabar abundance measured directly or inferred from mercury content, and what other mercury phases could affect that inference? boundary

Associated materials

Describe matrix, impurities and additions that affect interpretation or use.

Matrix and grade evidence

Tie grade claims to actual composition and the intended application.

  1. Which gangue minerals, binders, coatings or contaminants accompany the cinnabar? measurement
  2. Which documented composition limits define the claimed grade for the proposed use? action
Physical state and change Track the form and condition of cinnabar and evidence of transformation.

An intact crystal, a friable aggregate and a dispersed pigment require different examination and handling decisions.

Form and diagnostics

Record physical observations with their sampling limitations.

Specimen form

Describe particle or crystal form and the reliability of supporting diagnostic tests.

  1. Is the cinnabar present as crystals, massive material, a coating or powder, and what size range is observed? measurement
  2. Which colour, density or hardness observations concern cinnabar itself rather than its matrix or coating? boundary

Alteration and thermal events

Separate visible change from demonstrated chemical or structural change.

Change attribution

Record environmental history and tests needed to explain observed changes.

  1. What discolouration, surface products or loss of cohesion has occurred, and under which documented conditions? provenance
  2. What analysis distinguishes a surface coating, chemical alteration and a change of HgS phase? measurement
  3. For any reported thermal constant, what event, atmosphere and pressure were actually measured? measurement
Origin and representativeness Establish where the cinnabar came from and what an examined sample represents.

Phase identity does not establish natural origin, locality or uniformity across a specimen or lot.

Natural or synthetic origin

Support origin claims independently of mineral identification.

Origin evidence

Connect geological or production provenance to the particular material.

  1. What evidence supports natural, synthetic or mixed origin? provenance
  2. Which locality, collection or production records can be traced to this specimen or lot? provenance

Sampling and treatment history

Relate analytical results to heterogeneous material and prior interventions.

Sample representativeness

Record where analysis occurred and whether treatment changed the examined surface or fraction.

  1. Which grain, surface, depth or lot fraction was examined, and how representative is it? measurement
  2. Has washing, grinding, heating, restoration or coating changed the material since collection or production? provenance
Mercury-specific action basis Connect proposed actions to verified identity, physical form and applicable requirements.

Decisions must address the actual cinnabar-bearing material and operation rather than relying on its mineral name alone.

Identity and classification mapping

Resolve identifiers and hazard records at the correct material scope.

Applicable material records

Record authoritative identity and classification evidence without assuming universal applicability.

  1. Which verified CAS, PubChem and EC records apply, and do they distinguish α-HgS from mercury sulfide generally? definition
  2. Which current classification or supplier document applies to this composition, form and jurisdiction? provenance

Operation-dependent controls

Evaluate examination, disturbance and disposition using evidence specific to the proposed operation.

Handling and disposition decision

Make action eligibility conditional on documented exposure pathways and applicable controls.

  1. Does the proposed operation involve abrasion, airborne particles, heating or chemical treatment, and what exposure evidence addresses it? action
  2. Which exposure limits or monitoring criteria apply to the mercury species and route involved, with what units and averaging period? measurement
  3. What verified requirements govern containment, transfer or disposal of this particular specimen, powder or mixture? action
Evidence and external alignment What the world already says about this thing, gathered so the model can be checked against it.

A model that cannot be lined up against existing standards, identifiers and practice cannot be adopted by anyone who already uses them.

Reported evidence

Findings from the breadth pass, kept separate from the structural claims.

Check these first

Recalled without web access and unsourced; every item is a lead to verify.

  • This describes the mineral sense using recalled knowledge, without source consultation.
  • Verify substance identifiers and current hazard classifications against the actual specimen or product; mineral cinnabar, synthetic HgS and pigment mixtures need not have identical records.
  • Density and composition refer to relatively pure cinnabar; impurities affect bulk measurements, and thermal values require explicit atmosphere and phase-transition conditions.
  1. Which of these check these first hold for the sense of cinnabar this model covers, and on what evidence? provenance

Identifiers and schemes

Recalled without web access and unsourced; every item is a lead to verify.

  • Chemical formula - HgS - The formula is shared by other mercury(II) sulfide polymorphs; cinnabar specifically has the trigonal structure.
  • Polymorph designation - α-HgS - Distinguishes cinnabar from cubic β-HgS, the mineral metacinnabar.
  1. Which of these identifiers and schemes hold for the sense of cinnabar this model covers, and on what evidence? provenance

Standards and regulation

Recalled without web access and unsourced; every item is a lead to verify.

  • The Minamata Convention on Mercury, administered through the United Nations Environment Programme, addresses mercury supply, primary mercury mining, trade, uses, emissions and wastes.
  1. Which of these standards and regulation hold for the sense of cinnabar this model covers, and on what evidence? provenance

Real-world use

Recalled without web access and unsourced; every item is a lead to verify.

  • Ore for extracting mercury.
  • Historical source of red pigment for painting, decoration and lacquerware.
  • Mineral specimens for collections, teaching and geological research.
  • Historically used in some traditional medicines and alchemical preparations.
  1. Which of these real-world use hold for the sense of cinnabar this model covers, and on what evidence? provenance

Typical measurements

Recalled without web access and unsourced; every item is a lead to verify.

  • Ideal mercury mass fraction - 86.2 - %
  • Mohs hardness - 2-2.5 - Mohs scale
  • Density of relatively pure mineral - 8.0-8.2 - g/cm³
  1. Which of these typical measurements hold for the sense of cinnabar this model covers, and on what evidence? provenance

Failure modes and hazards

Recalled without web access and unsourced; every item is a lead to verify.

  • Heating or roasting can release toxic mercury vapour; roasting in air also produces sulfur dioxide.
  • Crushing, grinding or handling powdered material can generate mercury-containing dust.
  • Low water solubility does not make cinnabar harmless; risk depends on exposure route, processing and associated mercury species.
  • Mining and processing can contaminate soil, water and sediments with mercury.
  • Cinnabar-based pigments can darken or otherwise alter under some light and chemical exposure conditions.
  1. Which of these failure modes and hazards hold for the sense of cinnabar this model covers, and on what evidence? provenance

Regional variation

Recalled without web access and unsourced; every item is a lead to verify.

  • Mercury mining, mineral trade and mercury-containing waste requirements depend on jurisdiction and implementation of the Minamata Convention.
  • Historical pigment and medicinal uses differ among cultural traditions; those uses do not establish present-day authorization or safety.
  1. Which of these regional variation hold for the sense of cinnabar this model covers, and on what evidence? provenance

Neighbouring kinds and how to tell them apart

Recalled without web access and unsourced; every item is a lead to verify.

  • metacinnabar - The same chemical formula, HgS, but a cubic crystal structure and typically black appearance.
  • vermilion - A red pigment name, commonly referring to prepared or synthetic red HgS; cinnabar denotes the naturally occurring mineral.
  • mercury - The chemical element Hg; cinnabar is a crystalline compound of mercury and sulfur.
  • mercury ore - Rock or material worked for its mercury content; it may contain cinnabar mixed with other minerals.
  1. Which of these neighbouring kinds and how to tell them apart hold for the sense of cinnabar this model covers, and on what evidence? provenance

What the second pass must settle

  • Does an existing Vercy world model already own cinnabar or α-HgS, requiring this registry entry to link to that publication?
  • Should synthetic α-HgS be represented directly under this entry or through a related material model while sharing the same phase identity?
  • Which CAS, PubChem and EC records precisely match this scope, and which conflate multiple HgS phases or commercial preparations?
  • Which primary measurements establish thermal events and alteration mechanisms under relevant conditions, especially where discolouration is attributed to phase conversion?
  • Which current jurisdiction-specific classifications, exposure criteria and disposal requirements apply to natural specimens, powders and cinnabar-containing mixtures?