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Research draft

chromatography

vr.tr.chromatography · INF.MED

Let an agent explain chromatography and its principles, relay the main techniques, instrumentation and applications from analytical chemistry sources, describe the specialised methods the registry aliases name, and distinguish chromatography from electrophoresis, distillation, filtration and spectroscopy.

Thing Registry Information and virtual systems

Research draft, second pass

A second pass drafted this model: the structure a model of this thing needs, and what is known about it in the world. The line under this one says how the second half was obtained - researched against sources, or recalled without web access, in which case nothing here was read anywhere and every claim is a lead to verify. Unreviewed either way.

written by Claude from model knowledge without web access - no source was read, every claim is a lead to verify

Researched by: Claude

Purpose and description

Let an agent explain chromatography and its principles, relay the main techniques, instrumentation and applications from analytical chemistry sources, describe the specialised methods the registry aliases name, and distinguish chromatography from electrophoresis, distillation, filtration and spectroscopy.

A family of laboratory techniques for separating the components of a mixture by passing it in a mobile phase over a stationary phase with which the components interact differently, from paper and thin-layer chromatography to gas, liquid and ion chromatography, with related and specialised methods such as countercurrent chromatography, argentation chromatography using silver ions, micellar electrokinetic chromatography, field-flow fractionation including its asymmetric flow variant, and paper analytical devices for low-cost testing; chromatography is fundamental to analytical and preparative chemistry.

What it is for: Separating and analysing mixtures.

It can be explain principles; relay techniques and applications; describe specialised methods; distinguish related techniques.

Distinguishing features

Mobile and stationary phases

Differential retention

Analytical and preparative

Many variants

What it looks like

Columns, plates or instruments through which samples flow, producing chromatograms.

Physical character

invented: 1900-1903 note - Mikhail Tsvet

HPLC developed: 1960s-1970s note

Nobel Prize: 1952 year - Martin and Synge, partition chromatography

How it is recognised

Separation by differential interaction with a stationary phase

Gas, liquid, paper and thin-layer chromatography; countercurrent, argentation and micellar electrokinetic chromatography; field-flow fractionation; paper analytical devices

Electrophoresis uses electric fields; distillation uses boiling points; filtration uses size; spectroscopy measures light

Related models

is a kind of - in registry terms

analytical chemical technique

is a kind of - in registry terms

lab technique

was invented by - around 1900

Mikhail Tsvet

is often coupled with - for identification

mass spectrometry

In practice

Families and kinds

gas chromatography

liquid chromatography including HPLC

paper and thin-layer chromatography

ion and size-exclusion chromatography

countercurrent and argentation chromatography

micellar electrokinetic chromatography

field-flow fractionation and asymmetric flow FFF

paper analytical devices

Standards and regulation

Pharmacopoeia and ISO methods specifying chromatographic procedures

Laboratory accreditation standards

Failure modes and hazards

Confusing chromatography with electrophoresis

Registry aliases mixing related but distinct techniques

Method validation failures

Also called

field-flow fractionationAsymmetric flow field flow fractionationargentation chromatographyPaper Analytical DeviceCountercurrent chromatographymicellar electrokinetic chromatographySephadexsupercritical fluid chromatographyelectrochromatographyadsorption chromatographyaffinity chromatographyexpanded bed adsorptiongas chromatographymicellar electrokinetic capillary chromatography,gel chromatographytwo-dimensional chromatographyliquid chromatographyion chromatographyliquid chromatography-tandem mass spectrometrycapillary electrochromatographygas adsorption chromatographydye-ligand affinity chromatographylateral flow testgas chromatography-olfactometrymultidimensional chromatographyflame ionizationrapid separation liquid chromatographyMulti Dimensional Liquid Chromatographyreversed-phase chromatographyDEAE-cellulose chromatographyrapid solid-phase qualitative immunochromatography

Where this came from

wikidata · CC0 1.0

Also registered as vr.tr.chromatography

Drafted structure

Bundle to layer to finding to question, as the second pass will find it: 4 bundles · 8 layers · 8 findings · 16 questions.

Understand What chromatography is.

Science.

Definition

Definition.

Definition

Definition.

  1. What is chromatography, and how does it differ from electrophoresis, distillation, filtration and spectroscopy? definition
  2. Is the question about principles, a technique, instrumentation or an application? boundary

Techniques

Techniques.

Techniques

Techniques.

  1. What are gas, liquid, paper, thin-layer, ion, countercurrent, argentation and micellar electrokinetic chromatography, field-flow fractionation and paper analytical devices? definition
  2. Which entry fits the specific technique? action
Principles Principles.

Science.

Theory

Theory.

Theory

Theory.

  1. How do retention, selectivity, efficiency and resolution govern separations? provenance
  2. Which references are standard? provenance

Instruments

Instruments.

Instruments

Instruments.

  1. How are columns, detectors and coupled instruments such as GC-MS and LC-MS built? provenance
  2. Which sources are cited? provenance
Applications Applications.

Application.

Fields

Fields.

Fields

Fields.

  1. How is chromatography used in pharmaceuticals, food, environment, forensics and biochemistry? provenance
  2. Which entry fits the specific application? action

Methods

Method development.

Methods

Methods.

  1. How are chromatographic methods developed and validated? provenance
  2. Which entry fits analytical method validation? action
Context History.

Context.

History

History.

History

History.

  1. How did chromatography develop from Tsvet through Martin and Synge to modern instruments? provenance
  2. Which entry fits the history of analytical chemistry? action

Frontiers

Frontiers.

Frontiers

Frontiers.

  1. What are current developments such as ultra-high-performance LC and low-cost paper devices? provenance
  2. Which entry fits microfluidics? action

What the second pass must settle

  • Should field-flow fractionation and paper analytical device be separate primary entries?
  • How should analytical chemistry sources be linked?
  • The registry entry has merged aliases naming distinct techniques; should they be split off?