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Research draft

gadolinium

vr.tr.gadolinium · PHY.MAT

Let an agent identify gadolinium and its properties, relay isotopes, production and uses from reference sources, describe MRI contrast agents and their safety in general terms, and distinguish gadolinium from neighbouring lanthanides.

Thing Registry Physical world and living systems

Research draft, second pass

A second pass drafted this model: the structure a model of this thing needs, and what is known about it in the world. The line under this one says how the second half was obtained - researched against sources, or recalled without web access, in which case nothing here was read anywhere and every claim is a lead to verify. Unreviewed either way.

written by Claude from model knowledge without web access - no source was read, every claim is a lead to verify

Researched by: Claude

Purpose and description

Let an agent identify gadolinium and its properties, relay isotopes, production and uses from reference sources, describe MRI contrast agents and their safety in general terms, and distinguish gadolinium from neighbouring lanthanides.

A chemical element with symbol Gd and atomic number 64, a silvery lanthanide with the highest thermal neutron capture cross-section of any stable element, ferromagnetic below room temperature, obtained from monazite and bastnasite and used in gadolinium-based contrast agents for magnetic resonance imaging, in neutron shielding and reactor control, in magnetic refrigeration research, in phosphors and in alloys; gadolinium has six stable isotopes plus the very long-lived gadolinium-152, with radioactive isotopes from gadolinium-134 upward.

What it is for: MRI contrast, neutron capture, magnets and phosphors.

It can be relay properties and isotopes; explain production and uses; describe contrast agent safety in general terms; distinguish from other lanthanides.

Distinguishing features

Highest neutron capture

Room-temperature Curie point

MRI contrast use

Magnetocaloric effect

What it looks like

A silvery metal that tarnishes slowly in dry air.

Physical character

atomic number: 64 Z

standard atomic weight: 157.25 u

Curie temperature: about 20 degrees C

thermal neutron cross-section: about 49000 barns - natural mixture

How it is recognised

Element 64, symbol Gd

Lanthanide of MRI contrast and neutron capture

Europium and terbium are the neighbouring lanthanides

Related models

is a kind of - in registry terms

lanthanide

is a kind of - in registry terms

heavy metal

is used in - for MRI

gadolinium-based contrast agent

is adjacent to - element 65

terbium

In practice

Families and kinds

gadolinium metal and alloys

gadolinium compounds and chelates for MRI

stable isotopes from gadolinium-154 to gadolinium-160 and the long-lived gadolinium-152

radioactive isotopes such as gadolinium-134 to gadolinium-137 and gadolinium-166 and 167

gadolinium in phosphors and garnets

Identifiers

symbol Gd

CAS 7440-54-2

Standards and regulation

Drug regulation of gadolinium contrast agents, including restrictions on linear agents

Chemical safety data sheets

Nuclear material rules for neutron absorbers

Failure modes and hazards

Nephrogenic systemic fibrosis with some agents in kidney disease

Gadolinium retention and environmental release

Confusing with neighbouring lanthanides

Also called

gadolinium-166gadolinium-167gadolinium-134gadolinium-135gadolinium-136gadolinium-137gadolinium-138gadolinium-138mgadolinium-139gadolinium-139mgadolinium-140gadolinium-141gadolinium-141mgadolinium-142gadolinium-143gadolinium-143mgadolinium-144gadolinium-145gadolinium-145mgadolinium-146gadolinium-147gadolinium-147mgadolinium-148gadolinium-149gadolinium-150gadolinium-151gadolinium-153m1gadolinium-153m2gadolinium-155mgadolinium-156mgadolinium-164gadolinium-154gadolinium-157gadolinium-158gadolinium-163gadolinium-153gadolinium-160gadolinium-162gadolinium-165gadolinium-168

+8

Where this came from

wikidata · CC0 1.0

Also registered as vr.tr.gadolinium

Drafted structure

Bundle to layer to finding to question, as the second pass will find it: 4 bundles · 8 layers · 8 findings · 16 questions.

Identify What gadolinium is.

Identity.

Properties

Properties.

Properties

Properties.

  1. What are the physical, magnetic and nuclear properties of gadolinium? definition
  2. Is the question about gadolinium or a neighbouring lanthanide? boundary

Isotopes

Isotopes.

Isotopes

Isotopes.

  1. Which isotopes exist, and which have high neutron capture? definition
  2. Which entry fits the specific isotope? action
Source Occurrence and production.

Supply.

Occurrence

Occurrence.

Occurrence

Occurrence.

  1. Where does gadolinium occur, and how is it separated? provenance
  2. Which entry fits rare earth mining? action

Supply

Supply.

Supply

Supply.

  1. Who produces gadolinium, and how is it traded, with sources? measurement
  2. Which sources are cited? provenance
Use Uses.

Application.

Medical

MRI contrast.

Medical

Medical.

  1. How do gadolinium contrast agents work, and what safety issues have regulators addressed, in general terms? provenance
  2. Is the user asking about their own scan, which needs a clinician? boundary

Other

Nuclear, magnetic and other uses.

Other

Other.

  1. How is gadolinium used in neutron shielding, magnetic refrigeration and phosphors? provenance
  2. Which references are standard? provenance
Context History and environment.

Context.

Discovery

Discovery.

Discovery

Discovery.

  1. How was gadolinium discovered by Marignac in 1880 and named after Johan Gadolin? provenance
  2. Which entry fits the history of the rare earths? action

Environment

Environmental gadolinium.

Environment

Environment.

  1. What do studies report about anthropogenic gadolinium in rivers from medical use? provenance
  2. Which entry fits pharmaceutical pollution? action

What the second pass must settle

  • Should gadolinium contrast agent be a separate primary entry?
  • How should reference and regulatory sources be linked?
  • The registry entry has merged aliases naming isotopes; should they be split off?