{ "vercy": "1.0-draft", "publication": { "status": "research-draft", "adjudicationStatus": "unreviewed", "publishableCanonical": false, "generatedAt": "2026-09-12T09:12:42Z", "providers": [ "Codex" ], "breadth": "recalled by Codex without web access - no source was read", "missingProviders": [], "pass": 2, "cost": { "grok": { "seconds": 18.0, "error": "Reading additional input from stdin...\nOpenAI Codex v0.153.4\n--------\nworkdir: R:\\02_PROJECTS\\02_Meta_Models_Platforms\\Ver.cy\\current\\thing-registry-backlog\nmodel: gpt-6-astra\nprovider: openai\napproval: never\nsandbox: read-only\nreasoning effort: none\nreasoning summaries: none\nsession id: 01a094e2-c18e-7722-b2e4-89fdd3bad6f2\n--------\nuser\nDescribe what is already known about one registered thing. Answer as JSON only, no prose around it.\n\nThing: dioxation\nSense to describe: (none recorded)\nDomain code: PHY.MAT\nAlso known as: (none)\n\n\nContext for this batch of 1001 things:\n# Batch 043: 1001 regis", "usd": 0.0, "recall": true }, "codex": { "seconds": 79.7, "error": "Reading additional input from stdin...\nOpenAI Codex v0.153.4\n--------\nworkdir: R:\\02_PROJECTS\\02_Meta_Models_Platforms\\Ver.cy\\current\\thing-registry-backlog\nmodel: gpt-6-astra\nprovider: openai\napproval: never\nsandbox: read-only\nreasoning effort: none\nreasoning summaries: none\nsession id: 01a094e2-c188-7e02-b6d9-6789d7fc1725\n--------\nuser\nYou are drafting a Vercy meta-model for one registered thing. Answer as JSON only, no prose around it.\n\nThing: dioxation\nRegistry id: vr.tr.dioxation\nPlane / domain: PHY / PHY.MAT\nRegistry definition: (none recorded)\nNames folded into this entry: (none)\n\n\nCont" } }, "enrichment": { "pass": 3, "engine": "claude", "producedAt": "2026-10-06T12:00:00Z", "ingestedAt": "2026-10-06T08:50:42+00:00", "fields": [ "agent_conduct", "ethics", "failure_modes_and_hazards", "owners", "standards_and_regulation" ] }, "gate": { "passed": true, "version": "1.0", "at": "2026-10-07T10:10:29+00:00", "evidence": [ "completeness 1.00", "sense: Wikidata description", "2 live sources", "review by codex: pass" ] } }, "metaModel": { "id": "THING-Q2779034", "registryId": "vr.tr.dioxation", "name": "dioxation", "version": "0.1.0-research.1", "entryKind": "thing", "family": "Thing Registry", "domain": [ "PHY.MAT" ], "status": "research-draft" }, "canonicalUrl": "https://ver.cy/models/thing/q2779034/", "model": { "registry_id": "vr.tr.dioxation", "name": "dioxation", "purpose": "Enable an agent to recognise dioxation, assess the identity and condition of a material containing it, and determine which handling or use decisions require further evidence.", "definition": "Dioxation is a name used for dioxathion, an organophosphorus pesticide historically used to control insects and mites through inhibition of acetylcholinesterase.", "scope_statement": "This model owns vr.tr.dioxation in PHY / PHY.MAT as a chemical substance, using the dioxathion identity supported by the synonym mapping in [NIST Chemistry WebBook](https://webbook.nist.gov/cgi/cbook.cgi?Name=Dioxathion), while requiring confirmation against the registry's originating record.", "in_scope": [ "Chemical identity, identifiers and the dioxation-dioxathion name correspondence", "Cis/trans composition, substance grade, assay and impurities", "Physical properties and stability under specified conditions", "Substance-specific hazard evidence and exposure constraints", "Jurisdiction-specific substance status and links to authorised products" ], "out_of_scope": [ "Complete pesticide formulations and their co-formulants", "Pest-management programmes, application schedules and efficacy optimisation", "Manufacturing processes and synthesis instructions", "Clinical diagnosis and treatment of poisoning", "Separate models of dioxane, other pesticides and transformation products" ], "distinguishing_features": [ "Require agreement with the dioxathion identifier set, including CAS 78-34-2 and PubChem CID 6531, rather than accepting the name alone. [PubChem](https://pubchem.ncbi.nlm.nih.gov/compound/78-34-2)", "Check the molecular formula C12H26O6P2S4 and the substituted dioxane structure; a dioxane ring alone does not establish identity. [PubChem](https://pubchem.ncbi.nlm.nih.gov/compound/78-34-2)", "Check for the 1,4-dioxane-2,3-diyl bis(O,O-diethyl phosphorodithioate) connectivity rather than confusing the substance with unsubstituted dioxane. [NIST Chemistry WebBook](https://webbook.nist.gov/cgi/cbook.cgi?Name=Dioxathion)", "Distinguish a cis/trans substance mixture from an individually characterised isomer; preserve the stereochemical scope of each source. [NIST Chemistry WebBook](https://webbook.nist.gov/cgi/cbook.cgi?Name=Dioxathion)", "Determine whether a labelled material is the substance, technical material or a formulated product before applying purity, property or hazard data." ], "characteristics": [ { "name": "Identity correspondence", "kind": "relation", "unit_or_values": "Registry id linked to source record, CAS number, PubChem CID, verified EC number and structure identifier", "why_it_matters": "Prevents a spelling variant or product name from creating a second substance identity." }, { "name": "Stereochemical composition", "kind": "measurement", "unit_or_values": "Cis and trans fractions in mol% or mass%, with analytical basis; unresolved allowed", "why_it_matters": "Determines whether data from an isomer or mixture apply to the material." }, { "name": "Grade", "kind": "category", "unit_or_values": "Analytical reference material, purified substance, technical material or unspecified", "why_it_matters": "Separates the evidence needed for analytical use from that for handling technical material." }, { "name": "Dioxathion assay", "kind": "measurement", "unit_or_values": "Mass%, with method, uncertainty and cis/trans summation rule", "why_it_matters": "Establishes how much identified substance is present." }, { "name": "Impurity and transformation-product profile", "kind": "measurement", "unit_or_values": "Named components in mg/kg or mass%, with detection and quantification limits", "why_it_matters": "Makes non-parent contributions to material condition and hazard visible." }, { "name": "Physical state", "kind": "state", "unit_or_values": "Observed phase and homogeneity at recorded temperature and pressure", "why_it_matters": "Supports recognition of altered or unsuitable material." }, { "name": "Thermal behaviour", "kind": "measurement", "unit_or_values": "Melting or freezing range, boiling point and decomposition onset in °C, with pressure and method", "why_it_matters": "Prevents decomposition or mixture transitions from being reported as a pure-substance boiling or melting point." }, { "name": "Partitioning and volatility", "kind": "measurement", "unit_or_values": "Water solubility in mg/L, vapour pressure in Pa and log Kow, with temperature and material composition", "why_it_matters": "Supports evidence-based assessment of transfer between air, water and organic phases." }, { "name": "Hazard classification", "kind": "category", "unit_or_values": "Source-specific GHS classes, categories and statements, including jurisdiction and revision date", "why_it_matters": "Connects hazard decisions to the correct substance or mixture classification." }, { "name": "Exposure benchmark", "kind": "measurement", "unit_or_values": "Source-defined limit in mg/m³ or other stated units, with route, averaging period and jurisdiction; unestablished allowed", "why_it_matters": "Prevents use of an inapplicable or invented exposure limit." }, { "name": "Permitted activity status", "kind": "state", "unit_or_values": "Activity-specific authorised, restricted, prohibited, expired or unresolved, with jurisdiction and effective date", "why_it_matters": "Separates substance identification from permission to possess, supply or use it." } ], "affordances": [ "Resolve a dioxation label to a supported substance identity and flag conflicting identifiers.", "Assess whether analytical evidence establishes the stated assay and cis/trans composition.", "Select property and hazard evidence applicable to the material's grade and composition.", "Flag material whose assay, impurity profile or storage history requires reassessment.", "Check a proposed activity against current jurisdictional evidence and relevant product authorisation.", "Link a formulation or residue result to this substance without merging their distinct models." ], "agent_conduct": { "may": [ "Explain what dioxathion is, its history as a pesticide and its regulatory status from official sources.", "Identify old stocks for safe collection by authorized hazardous waste services.", "Direct people to poison control or emergency services after a suspected exposure." ], "must_not": [ "Give any procedure, dose or method for making, applying or obtaining it.", "Help anyone use it to poison people or animals.", "Recommend using obsolete or banned pesticide stocks.", "Advise disposal into drains, soil or ordinary waste." ], "requires_human": [ "Handling or moving old pesticide stocks, which must be done by authorized services." ] }, "ethics": { "considerations": [ "Organophosphate pesticides have poisoned farm workers and families, often in low-income countries.", "Obsolete stocks contaminate soil and water if abandoned." ], "affected_parties": [ "Farm workers and families", "Children near stored pesticides", "Wildlife and water" ] }, "owners": { "steward": "The holder of any stock, under the duties set by pesticide and hazardous waste law.", "master_systems": [ "National pesticide registration databases" ] }, "failure_modes_and_hazards": [ "Inhibits acetylcholinesterase and can cause serious poisoning by contact, inhalation or swallowing.", "Toxic to aquatic life and wildlife." ], "standards_and_regulation": [ "Globally Harmonized System of Classification and Labelling of Chemicals (GHS), United Nations." ], "what_it_is_for": [ "Dioxation is a name used for dioxathion, an organophosphorus pesticide historically used against insects and mites.", "It may be encountered in historical pesticide records, legacy chemical stocks and environmental residue investigations." ], "visual_identification": [ "A container label or associated inventory may identify the substance as dioxathion or the alternative spelling dioxation.", "An accompanying composition label may distinguish the named active ingredient from a formulated mixture, but visual inspection cannot confirm chemical identity." ] }, "sources": [ { "id": "wikidata", "title": "Wikidata item Q2779034: dioxation", "url": "https://www.wikidata.org/wiki/Q2779034", "url_status": "live", "what_it_supports": "identity and sense of the item", "checked_by": "wikidata-api" }, { "id": "wikipedia-en", "title": "Wikipedia: Dioxathion", "url": "https://en.wikipedia.org/wiki/Dioxathion", "url_status": "live", "what_it_supports": "general description of the item", "checked_by": "wikidata-api sitelink" } ], "structure": { "bundles": [ { "id": "dioxation-identity", "name": "Dioxation identity", "description": "Resolve the registry name to a chemical identity without multiplying synonymous entries.", "rationale": "The registry supplies no definition, so the external synonym match must remain traceable.", "layers": [ { "id": "name-correspondence", "name": "Name correspondence", "description": "Connect the registry term to the dioxathion reference identity.", "findings": [ { "id": "supported-synonym-match", "name": "Supported synonym match", "description": "NIST lists Dioxation among the names for dioxathion; the original registry record must establish whether that is the intended referent. [NIST Chemistry WebBook](https://webbook.nist.gov/cgi/cbook.cgi?Name=Dioxathion)", "questions": [ { "text": "Which originating record supplied the name dioxation to vr.tr.dioxation?", "kind": "provenance", "id": "supported-synonym-match-q01" }, { "text": "Do that record's identifiers resolve to dioxathion rather than a product or another substance?", "kind": "definition", "id": "supported-synonym-match-q02" } ] } ] }, { "id": "structure-boundary", "name": "Structure boundary", "description": "Define the connectivity and stereochemical coverage of the registered substance.", "findings": [ { "id": "connectivity-and-isomer-scope", "name": "Connectivity and isomer scope", "description": "Require structure-level agreement and explicit treatment of unspecified stereochemistry, individual isomers and mixtures.", "questions": [ { "text": "Which reference structure and stereochemical specification define this entry?", "kind": "definition", "id": "connectivity-and-isomer-scope-q01" }, { "text": "Does the entry cover the cis/trans mixture, and how are isomer-specific records linked without splitting registry granularity?", "kind": "boundary", "id": "connectivity-and-isomer-scope-q02" } ] } ] } ] }, { "id": "dioxathion-material-composition", "name": "Dioxathion material composition", "description": "Describe the composition of material assigned to the substance identity.", "rationale": "A name match cannot establish assay, isomer proportions or the suitability of technical material.", "layers": [ { "id": "assay-and-isomers", "name": "Assay and isomers", "description": "Record parent-substance content and its stereochemical basis.", "findings": [ { "id": "composition-supported-by-analysis", "name": "Composition supported by analysis", "description": "Keep total dioxathion assay distinct from the proportions and analytical resolution of its isomers.", "questions": [ { "text": "What method measures total dioxathion, and does its calibration cover the relevant isomers?", "kind": "measurement", "id": "composition-supported-by-analysis-q01" }, { "text": "What cis/trans proportions are measured, and which components remain unresolved?", "kind": "measurement", "id": "composition-supported-by-analysis-q02" } ] } ] }, { "id": "technical-material-boundary", "name": "Technical material boundary", "description": "Separate substance impurities from intentionally added formulation ingredients.", "findings": [ { "id": "non-parent-components", "name": "Non-parent components", "description": "Identify non-parent components and link formulated products to their own composition records.", "questions": [ { "text": "Which detected components are impurities or transformation products, and which are intentionally added ingredients?", "kind": "boundary", "id": "non-parent-components-q01" }, { "text": "Which certificate or analytical report supports the declared grade and impurity limits?", "kind": "provenance", "id": "non-parent-components-q02" } ] } ] } ] }, { "id": "physical-behaviour-and-change", "name": "Physical behaviour and change", "description": "Qualify physical constants and material changes by composition and conditions.", "rationale": "Unqualified constants can wrongly transfer results between purified isomers, mixtures and technical material.", "layers": [ { "id": "conditioned-physical-properties", "name": "Conditioned physical properties", "description": "Attach material identity and experimental conditions to phase, thermal and partitioning measurements.", "findings": [ { "id": "applicable-property-values", "name": "Applicable property values", "description": "Accept property values only with enough context to assess their applicability to the recorded material.", "questions": [ { "text": "Which phase and thermal-transition measurements apply to the stated grade and isomer composition?", "kind": "measurement", "id": "applicable-property-values-q01" }, { "text": "At what temperature, pressure and medium conditions were solubility, vapour pressure and partitioning measured?", "kind": "measurement", "id": "applicable-property-values-q02" } ] } ] }, { "id": "parent-substance-persistence", "name": "Parent-substance persistence", "description": "Track evidence of parent loss and changes in composition during storage or environmental contact.", "findings": [ { "id": "verified-material-change", "name": "Verified material change", "description": "Distinguish demonstrated transformation from assumptions based on chemical class.", "questions": [ { "text": "What studies establish changes in dioxathion assay under specified light, temperature, pH or moisture conditions?", "kind": "provenance", "id": "verified-material-change-q01" }, { "text": "What observed change or elapsed validated storage interval triggers reanalysis of this material?", "kind": "action", "id": "verified-material-change-q02" } ] } ] } ] }, { "id": "hazard-and-exposure-evidence", "name": "Hazard and exposure evidence", "description": "Organise toxicological and environmental evidence that constrains interaction with dioxathion.", "rationale": "Decisions need evidence for the identified substance and material, including unresolved hazard questions.", "layers": [ { "id": "toxicological-applicability", "name": "Toxicological applicability", "description": "Connect hazard endpoints to tested composition, exposure route and evidence quality.", "findings": [ { "id": "substance-specific-endpoints", "name": "Substance-specific endpoints", "description": "Require direct evidence for acute toxicity, cholinesterase effects and other relevant endpoints before assigning conclusions.", "questions": [ { "text": "Which authoritative assessments establish dioxathion's toxicological endpoints, including any cholinesterase effects?", "kind": "provenance", "id": "substance-specific-endpoints-q01" }, { "text": "What composition, route, duration and endpoint does each reported toxicity value describe?", "kind": "measurement", "id": "substance-specific-endpoints-q02" } ] } ] }, { "id": "exposure-and-release-constraints", "name": "Exposure and release constraints", "description": "Connect applicable exposure benchmarks and environmental evidence to handling decisions.", "findings": [ { "id": "supported-control-basis", "name": "Supported control basis", "description": "Record the source and applicability of controls without deriving safe exposure from missing data.", "questions": [ { "text": "Which current exposure limits, route-specific precautions and GHS classifications apply to this material?", "kind": "provenance", "id": "supported-control-basis-q01" }, { "text": "Which environmental toxicity and fate evidence constrains containment and disposal of dioxathion-bearing material?", "kind": "action", "id": "supported-control-basis-q02" } ] } ] } ] }, { "id": "activity-authorisation", "name": "Activity authorisation", "description": "Determine what legal and product-specific evidence is required for a proposed activity.", "rationale": "A recognised pesticide substance identity does not establish current permission for a particular use.", "layers": [ { "id": "jurisdictional-substance-status", "name": "Jurisdictional substance status", "description": "Track dated regulatory decisions for the dioxathion identity.", "findings": [ { "id": "dated-activity-status", "name": "Dated activity status", "description": "Represent possession, import, supply, research use and disposal as separately evidenced activities.", "questions": [ { "text": "Which official record establishes the substance's status in the relevant jurisdiction on the decision date?", "kind": "provenance", "id": "dated-activity-status-q01" }, { "text": "Does that record authorise, restrict or prohibit the particular proposed activity?", "kind": "action", "id": "dated-activity-status-q02" } ] } ] }, { "id": "product-use-boundary", "name": "Product use boundary", "description": "Keep substance-level information separate from formulation-specific authorisation.", "findings": [ { "id": "product-specific-permission", "name": "Product-specific permission", "description": "Require a linked product authorisation when the decision concerns application of a formulation.", "questions": [ { "text": "Which exact product, formulation and current authorisation are associated with the intended application?", "kind": "boundary", "id": "product-specific-permission-q01" }, { "text": "What label conditions must the product or application model verify before the activity can proceed?", "kind": "action", "id": "product-specific-permission-q02" } ] } ] } ] }, { "id": "evidence-and-external-alignment", "name": "Evidence and external alignment", "description": "What the world already says about this thing, gathered so the model can be checked against it.", "rationale": "A model that cannot be lined up against existing standards, identifiers and practice cannot be adopted by anyone who already uses them.", "layers": [ { "id": "reported-evidence", "name": "Reported evidence", "description": "Findings from the breadth pass, kept separate from the structural claims.", "findings": [ { "id": "evidence-confidence-notes", "name": "Check these first", "description": "Recalled without web access and unsourced; every item is a lead to verify.", "evidence": [ "The first check should establish that the registry label dioxation denotes dioxathion; no sense or identifier was supplied.", "Uses listed are historical and do not establish current authorization in any jurisdiction.", "Exact identifiers, stereoisomer composition, physical constants, exposure limits, and regulatory classifications require verification; none were researched here." ], "questions": [ { "id": "evidence-confidence-notes-q01", "text": "Which of these check these first hold for the sense of dioxation this model covers, and on what evidence?", "kind": "provenance" } ] }, { "id": "evidence-identifiers", "name": "Identifiers and schemes", "description": "Recalled without web access and unsourced; every item is a lead to verify.", "evidence": [ { "scheme": "CAS Registry Number", "value_or_pattern": "Up to seven digits, followed by a hyphen, two digits, another hyphen, and one check digit", "note": "Confirm the substance identity and applicable stereoisomer coverage before assigning a specific number." } ], "questions": [ { "id": "evidence-identifiers-q01", "text": "Which of these identifiers and schemes hold for the sense of dioxation this model covers, and on what evidence?", "kind": "provenance" } ] }, { "id": "evidence-real-world-use", "name": "Real-world use", "description": "Recalled without web access and unsourced; every item is a lead to verify.", "evidence": [ "Historical agricultural insecticide and acaricide.", "Historical control of external parasites on livestock." ], "questions": [ { "id": "evidence-real-world-use-q01", "text": "Which of these real-world use hold for the sense of dioxation this model covers, and on what evidence?", "kind": "provenance" } ] }, { "id": "evidence-failure-modes-and-hazards", "name": "Failure modes and hazards", "description": "Recalled without web access and unsourced; every item is a lead to verify.", "evidence": [ "Acetylcholinesterase inhibition can cause acute cholinergic poisoning.", "Occupational exposure can occur during mixing and application, including through skin contact.", "Pesticide formulations can introduce additional hazards from solvents and other ingredients." ], "questions": [ { "id": "evidence-failure-modes-and-hazards-q01", "text": "Which of these failure modes and hazards hold for the sense of dioxation this model covers, and on what evidence?", "kind": "provenance" } ] }, { "id": "evidence-neighbours", "name": "Neighbouring kinds and how to tell them apart", "description": "Recalled without web access and unsourced; every item is a lead to verify.", "evidence": [ { "name": "dioxathion", "difference": "Likely an alternative spelling of the same substance; verify synonymy before treating these as separate registry entries." }, { "name": "dioxane", "difference": "Dioxane denotes oxygen-containing cyclic ethers, not this organophosphorus pesticide." }, { "name": "dioxation-containing pesticide formulation", "difference": "A formulation contains the active substance together with other ingredients and has its own concentration and product identity." } ], "questions": [ { "id": "evidence-neighbours-q01", "text": "Which of these neighbouring kinds and how to tell them apart hold for the sense of dioxation this model covers, and on what evidence?", "kind": "provenance" } ] } ] } ] } ] }, "openQuestions": [ "Does the registry's originating record confirm the externally supported dioxation-dioxathion synonym mapping, and is an existing Vercy model already authoritative for it?", "What stereochemical scope, technical-grade specification and impurity profile should define material conformity for this entry?", "Which reliable physical-property measurements apply to each relevant grade, and where do decomposition or mixture effects prevent a single reported constant?", "Which authoritative sources establish current hazard classifications, exposure benchmarks, environmental endpoints and validated stability conditions?", "Which jurisdictions and activities need coverage, and what current official records establish substance restrictions and any product authorisations?" ], "statistics": { "bundles": 6, "layers": 11, "findings": 15, "questions": 25 } }