{ "vercy": "1.0-draft", "publication": { "status": "research-draft", "adjudicationStatus": "unreviewed", "publishableCanonical": false, "generatedAt": "2026-09-12T10:24:30Z", "providers": [ "Codex" ], "breadth": "recalled by Codex without web access - no source was read", "missingProviders": [], "pass": 2, "cost": { "grok": { "seconds": 15.5, "error": "Reading additional input from stdin...\nOpenAI Codex v0.153.4\n--------\nworkdir: R:\\02_PROJECTS\\02_Meta_Models_Platforms\\Ver.cy\\current\\thing-registry-backlog\nmodel: gpt-6-astra\nprovider: openai\napproval: never\nsandbox: read-only\nreasoning effort: none\nreasoning summaries: none\nsession id: 01a09524-81af-7361-801e-f0ed5d4a7aed\n--------\nuser\nDescribe what is already known about one registered thing. Answer as JSON only, no prose around it.\n\nThing: iceane\nSense to describe: (none recorded)\nDomain code: PHY.MAT\nAlso known as: (none)\n\n\nContext for this batch of 1001 things:\n# Batch 043: 1001 register", "usd": 0.0, "recall": true }, "codex": { "seconds": 78.3, "error": "Reading additional input from stdin...\nOpenAI Codex v0.153.4\n--------\nworkdir: R:\\02_PROJECTS\\02_Meta_Models_Platforms\\Ver.cy\\current\\thing-registry-backlog\nmodel: gpt-6-astra\nprovider: openai\napproval: never\nsandbox: read-only\nreasoning effort: none\nreasoning summaries: none\nsession id: 01a09524-81b4-7563-ab4b-1ee2effeaad4\n--------\nuser\nYou are drafting a Vercy meta-model for one registered thing. Answer as JSON only, no prose around it.\n\nThing: iceane\nRegistry id: vr.tr.iceane\nPlane / domain: PHY / PHY.MAT\nRegistry definition: (none recorded)\nNames folded into this entry: (none)\n\n\nContext fo" } }, "enrichment": { "pass": 3, "engine": "claude", "producedAt": "2026-10-06T12:00:00Z", "ingestedAt": "2026-10-06T08:55:21+00:00", "fields": [ "agent_conduct", "ethics", "failure_modes_and_hazards", "owners", "visual_identification" ] }, "revisions": [ { "at": "2026-10-07T11:28:53+00:00", "engine": "codex", "fields": [ "definition" ], "answering_review": "e9d2436983749cfdaad98483da8de1bc5ecd01792c07a20f89a59239ed7e6f0c" } ], "gate": { "passed": true, "version": "1.0", "at": "2026-10-07T12:16:31+00:00", "evidence": [ "completeness 1.00", "sense: Wikidata description", "2 live sources", "review by codex: pass" ] } }, "metaModel": { "id": "THING-Q2855757", "registryId": "vr.tr.iceane", "name": "iceane", "version": "0.1.0-research.1", "entryKind": "thing", "family": "Thing Registry", "domain": [ "PHY.MAT" ], "status": "research-draft" }, "canonicalUrl": "https://ver.cy/models/thing/q2855757/", "model": { "registry_id": "vr.tr.iceane", "name": "iceane", "purpose": "Enable an agent to identify iceane, assess the identity and condition of an iceane sample, and determine which investigations or uses its evidence supports.", "definition": "Iceane is a saturated tetracyclic cage hydrocarbon with molecular formula C12H18 whose carbon framework resembles a fragment of the hexagonal ice lattice.", "scope_statement": "This model owns vr.tr.iceane in PHY / PHY.MAT: the parent cage hydrocarbon and the evidence needed to assess its samples, properties and suitability for an intended operation.", "in_scope": [ "Parent molecular identity, cage connectivity and structural representations", "Reconciliation of iceane names and chemical identifiers", "Sample identity, purity and synthesis-derived impurities", "Physical state and condition-dependent measured properties", "Evidence supporting handling, characterization and research use" ], "out_of_scope": [ "Water ice and its crystal phases", "Other cage hydrocarbons as independently identified substances", "Substituted iceanes and compounds containing an iceane substructure", "Detailed synthesis procedures and reaction equipment", "Commercial formulations containing iceane" ], "distinguishing_features": [ "Require the parent formula C12H18 and the connectivity designated tetracyclo[5.3.1.1^2,6.0^4,9]dodecane; formula alone cannot distinguish structural isomers. [J-GLOBAL](https://jglobal.jst.go.jp/en/detail?JGLOBAL_ID=200907012064111831)", "Resolve wurtzitane as a chemical synonym and reconcile CAS 53283-19-5 with the structure rather than treating the alternate name as a separate registered thing. [FDA substance record](https://precision.fda.gov/uniisearch/srs/unii/QV8UUF9ZUY)", "Reject identification by resemblance to ice: the registered substance is a carbon-and-hydrogen molecule, not frozen water. [J-GLOBAL](https://jglobal.jst.go.jp/en/detail?JGLOBAL_ID=200907012064111831)", "Require the complete parent molecule, not merely an iceane skeleton inside a larger molecule; a published skeleton-construction study explicitly describes the latter. [Hamon and Spurr](https://doi.org/10.1039/C39820000372)" ], "characteristics": [ { "name": "Parent molecular identity", "kind": "category", "unit_or_values": "C12H18; tetracyclo[5.3.1.1^2,6.0^4,9]dodecane", "why_it_matters": "Sets the formula and connectivity required for an iceane assignment. [J-GLOBAL](https://jglobal.jst.go.jp/en/detail?JGLOBAL_ID=200907012064111831)" }, { "name": "Identifier correspondence", "kind": "relation", "unit_or_values": "Registry vr.tr.iceane; CAS 53283-19-5; UNII QV8UUF9ZUY; other identifiers require reconciliation", "why_it_matters": "Connects records without assuming that a database identifier establishes sample identity or approval. [FDA substance record](https://precision.fda.gov/uniisearch/srs/unii/QV8UUF9ZUY)" }, { "name": "Structural representation completeness", "kind": "state", "unit_or_values": "Connectivity recorded; stereochemical encoding assessed; unresolved discrepancies", "why_it_matters": "Prevents structure-file differences from becoming unsupported identity distinctions." }, { "name": "Iceane content", "kind": "measurement", "unit_or_values": "Mass fraction or molar fraction; chromatographic area percent recorded separately with method", "why_it_matters": "Distinguishes a verified parent sample from a crude preparation or mixture." }, { "name": "Residual precursor and byproduct profile", "kind": "relation", "unit_or_values": "Identified impurity, concentration, detection limit and preparation record", "why_it_matters": "Connects sample suitability to impurities actually supported by its preparation and analysis." }, { "name": "Physical state and thermal behavior", "kind": "state", "unit_or_values": "Observed phase at stated temperature and pressure; thermal event classified as melting, sublimation, decomposition or unresolved", "why_it_matters": "Prevents an unqualified thermal observation from being used as a transferable material constant." }, { "name": "Solubility", "kind": "measurement", "unit_or_values": "mol/L or g/L, with solvent, temperature and measurement method", "why_it_matters": "Supports preparation of analytical solutions and interpretation of incomplete dissolution." }, { "name": "Hazard evidence status", "kind": "state", "unit_or_values": "Iceane-specific evidence; explicit analogue inference; conflicting evidence; unknown", "why_it_matters": "Keeps absent substance-specific data distinct from evidence of low hazard." } ], "affordances": [ "Resolve an iceane-labelled record against a reference molecular structure and identifier mapping.", "Assess whether analytical evidence supports parent iceane rather than a precursor, derivative or isomer.", "Compare sample purity and impurity profiles against the requirements of a proposed study.", "Select characterization conditions using documented thermal behavior and solvent compatibility.", "Link a sample to its preparation and subsequent transformations without merging their substance identities.", "Flag missing evidence that prevents a justified handling or research-use decision." ], "agent_conduct": { "may": [ "Explain iceane's cage structure and its resemblance to a fragment of the hexagonal ice lattice.", "Report experimental findings with their sources." ], "must_not": [ "Present computed or speculative properties as measured.", "Handle research samples without laboratory safety rules.", "Confuse iceane with water ice in teaching material." ], "requires_human": [ "Approving disposal of research samples." ] }, "ethics": { "considerations": [ "Precision about unusual molecules keeps chemistry teaching honest.", "Laboratory safety protects students and researchers." ], "affected_parties": [ "Students", "Researchers", "Laboratory workers" ] }, "owners": { "steward": "Researchers who hold samples; nobody owns the structure.", "master_systems": [] }, "visual_identification": [ "Identified by container label, chemical name and identifier, and certificate of analysis rather than by appearance alone." ], "failure_modes_and_hazards": [ "Misreported properties.", "Flammability typical of hydrocarbons." ], "what_it_is_for": [ "Iceane is encountered in specialist organic chemistry research on cage hydrocarbons and molecular structure.", "Its rigid carbon framework provides a subject for studying synthesis, stereochemistry and relationships between molecular geometry and properties." ], "standards_and_regulation": [ "The Globally Harmonized System of Classification and Labelling of Chemicals, published by the United Nations, provides the framework for classifying and communicating chemical hazards where implemented by the relevant jurisdiction." ] }, "sources": [ { "id": "wikidata", "title": "Wikidata item Q2855757: iceane", "url": "https://www.wikidata.org/wiki/Q2855757", "url_status": "live", "what_it_supports": "identity and sense of the item", "checked_by": "wikidata-api" }, { "id": "wikipedia-en", "title": "Wikipedia: Iceane", "url": "https://en.wikipedia.org/wiki/Iceane", "url_status": "live", "what_it_supports": "general description of the item", "checked_by": "wikidata-api sitelink" } ], "structure": { "bundles": [ { "id": "iceane-identity", "name": "Iceane identity", "description": "Establish the precise parent substance represented by the registry entry.", "rationale": "The registry has no definition, so name matching must be anchored to chemical structure.", "layers": [ { "id": "parent-cage", "name": "Parent cage", "description": "Define the molecular graph and the structural information needed to recognize it.", "findings": [ { "id": "reference-structure", "name": "Reference structure", "description": "Use the published parent connectivity as the identity anchor, retaining the original representation and its source. [J-GLOBAL](https://jglobal.jst.go.jp/en/detail?JGLOBAL_ID=200907012064111831)", "questions": [ { "text": "Which reference structure fixes the carbon connectivity intended by iceane?", "kind": "definition", "id": "reference-structure-q01" }, { "text": "Does each imported representation preserve that connectivity and adequately express any relevant stereochemistry?", "kind": "boundary", "id": "reference-structure-q02" } ] } ] }, { "id": "name-resolution", "name": "Name resolution", "description": "Connect chemical synonyms and external identifiers to the single registry entry.", "findings": [ { "id": "identifier-agreement", "name": "Identifier agreement", "description": "Keep chemical synonym mappings separate from registry-folding decisions and record unresolved identifier differences.", "questions": [ { "text": "Which authoritative records map iceane and wurtzitane to the same parent structure?", "kind": "provenance", "id": "identifier-agreement-q01" }, { "text": "Do CAS, PubChem, UNII and any EC records refer to the same structure at the same specificity?", "kind": "boundary", "id": "identifier-agreement-q02" } ] } ] } ] }, { "id": "parent-versus-related-cages", "name": "Parent versus related cages", "description": "Set boundaries between iceane, structural analogues and molecules incorporating its skeleton.", "rationale": "A cage resemblance or an iceane-substructure claim does not establish parent-substance identity.", "layers": [ { "id": "cage-comparison", "name": "Cage comparison", "description": "Compare complete molecular graphs rather than names or visual resemblance.", "findings": [ { "id": "structural-discrimination", "name": "Structural discrimination", "description": "Require atom counts, bonding and connectivity to distinguish iceane from other cage hydrocarbons and same-formula isomers.", "questions": [ { "text": "Which graph differences distinguish the candidate from the reference iceane structure?", "kind": "boundary", "id": "structural-discrimination-q01" }, { "text": "Which experimental observations discriminate iceane from the plausible alternative structures in this sample?", "kind": "measurement", "id": "structural-discrimination-q02" } ] } ] }, { "id": "derivative-boundary", "name": "Derivative boundary", "description": "Separate parent iceane from substituted compounds and larger skeleton-containing molecules.", "findings": [ { "id": "whole-molecule-test", "name": "Whole-molecule test", "description": "A report of constructing the iceane skeleton may concern a larger product rather than isolated parent iceane. [Hamon and Spurr](https://doi.org/10.1039/C39820000372)", "questions": [ { "text": "Does the reported product match the entire parent molecule or contain only its carbon substructure?", "kind": "boundary", "id": "whole-molecule-test-q01" }, { "text": "What evidence demonstrates isolation of parent iceane rather than an intermediate or derivative?", "kind": "provenance", "id": "whole-molecule-test-q02" } ] } ] } ] }, { "id": "iceane-sample-authentication", "name": "Iceane sample authentication", "description": "Connect molecular identity to an actual preparation or acquired sample.", "rationale": "An iceane label or successful route proposal cannot establish the composition of a particular sample.", "layers": [ { "id": "analytical-assignment", "name": "Analytical assignment", "description": "Assess orthogonal analytical evidence for the parent cage.", "findings": [ { "id": "spectral-identity", "name": "Spectral identity", "description": "Record reference comparisons and assignments without inventing characteristic peaks or treating formula agreement as structural proof.", "questions": [ { "text": "Which measured NMR and mass-spectrometric data support the iceane assignment, and under what conditions?", "kind": "measurement", "id": "spectral-identity-q01" }, { "text": "Which primary reference supplies the comparison spectra or structural determination?", "kind": "provenance", "id": "spectral-identity-q02" }, { "text": "What additional analysis would resolve an ambiguous cage assignment?", "kind": "action", "id": "spectral-identity-q03" } ] } ] }, { "id": "preparation-and-purity", "name": "Preparation and purity", "description": "Assess parent content and route-specific contamination.", "findings": [ { "id": "sample-composition", "name": "Sample composition", "description": "Link measured iceane content, residual solvents and identified reaction residues to the actual sample history.", "questions": [ { "text": "What quantitative method establishes iceane content, and what uncertainty or response-factor limitations apply?", "kind": "measurement", "id": "sample-composition-q01" }, { "text": "Which precursors, byproducts or solvents are plausible from this preparation, and which were actually detected?", "kind": "provenance", "id": "sample-composition-q02" }, { "text": "Does the measured composition meet the requirements of the proposed structural or physical-property study?", "kind": "action", "id": "sample-composition-q03" } ] } ] } ] }, { "id": "iceane-physical-behavior", "name": "Iceane physical behavior", "description": "Capture experimentally supported phase, thermal and solvent-dependent behavior.", "rationale": "The cage identity alone does not establish conditions for storage, purification or measurement.", "layers": [ { "id": "thermal-events", "name": "Thermal events", "description": "Distinguish phase changes from mass loss and chemical change.", "findings": [ { "id": "event-assignment", "name": "Event assignment", "description": "Treat reported melting or sublimation behavior as evidence to verify with pressure, apparatus and sample composition.", "questions": [ { "text": "Which primary measurements establish iceane melting, sublimation or decomposition, with temperature and pressure?", "kind": "measurement", "id": "event-assignment-q01" }, { "text": "Was the material recovered after heating confirmed as unchanged parent iceane?", "kind": "measurement", "id": "event-assignment-q02" }, { "text": "What documented thermal range supports the proposed drying, purification or measurement operation?", "kind": "action", "id": "event-assignment-q03" } ] } ] }, { "id": "solution-and-solid-state", "name": "Solution and solid state", "description": "Keep solution properties and solid-state observations distinct.", "findings": [ { "id": "conditioned-property-records", "name": "Conditioned property records", "description": "Attach solvent, temperature, phase and method to each property rather than inferring bulk behavior from a cage drawing.", "questions": [ { "text": "What measured solubility supports the solvent and concentration proposed for iceane analysis?", "kind": "measurement", "id": "conditioned-property-records-q01" }, { "text": "Which observations establish the sample's solid form, and is any claimed polymorphism experimentally supported?", "kind": "measurement", "id": "conditioned-property-records-q02" } ] } ] } ] }, { "id": "iceane-use-decisions", "name": "Iceane use decisions", "description": "Connect available evidence to handling decisions and defensible research uses.", "rationale": "Neither a cage-hydrocarbon analogy nor a registry listing establishes iceane-specific safety or suitability.", "layers": [ { "id": "handling-evidence", "name": "Handling evidence", "description": "Evaluate substance-specific hazard information and its applicability to the sample.", "findings": [ { "id": "hazard-and-status-gaps", "name": "Hazard and status gaps", "description": "Record the basis and jurisdiction of hazard or regulatory claims; UNII assignment itself does not imply regulatory approval. [FDA substance record](https://precision.fda.gov/uniisearch/srs/unii/QV8UUF9ZUY)", "questions": [ { "text": "Which iceane-specific sources establish hazard classifications, exposure limits or storage incompatibilities?", "kind": "provenance", "id": "hazard-and-status-gaps-q01" }, { "text": "Does the available safety information cover parent iceane at this purity, or a mixture with materially different hazards?", "kind": "boundary", "id": "hazard-and-status-gaps-q02" }, { "text": "What further assessment is required before the intended handling operation can be justified?", "kind": "action", "id": "hazard-and-status-gaps-q03" } ] } ] }, { "id": "research-fitness", "name": "Research fitness", "description": "Determine whether iceane evidence supports the intended experimental or computational role.", "findings": [ { "id": "supported-research-role", "name": "Supported research role", "description": "Separate demonstrated uses from proposed cage-structure comparisons, computed properties and unsupported applications.", "questions": [ { "text": "Is iceane serving as an isolated experimental substance, a synthetic target or a computational structure in the proposed work?", "kind": "definition", "id": "supported-research-role-q01" }, { "text": "Which conclusions about cage geometry or energetics are measured, and which depend on a stated computational method?", "kind": "provenance", "id": "supported-research-role-q02" }, { "text": "What identity, purity and property evidence must be obtained before this sample can serve the intended research role?", "kind": "action", "id": "supported-research-role-q03" } ] } ] } ] }, { "id": "evidence-and-external-alignment", "name": "Evidence and external alignment", "description": "What the world already says about this thing, gathered so the model can be checked against it.", "rationale": "A model that cannot be lined up against existing standards, identifiers and practice cannot be adopted by anyone who already uses them.", "layers": [ { "id": "reported-evidence", "name": "Reported evidence", "description": "Findings from the breadth pass, kept separate from the structural claims.", "findings": [ { "id": "evidence-confidence-notes", "name": "Check these first", "description": "Recalled without web access and unsourced; every item is a lead to verify.", "evidence": [ "This description is based on recall; no sources were consulted.", "Verify the systematic name, stereochemical specification and registry identifiers before assigning an authoritative chemical identity.", "Physical constants, toxicity, hazard classifications and commercial applications are not established here." ], "questions": [ { "id": "evidence-confidence-notes-q01", "text": "Which of these check these first hold for the sense of iceane this model covers, and on what evidence?", "kind": "provenance" } ] }, { "id": "evidence-identifiers", "name": "Identifiers and schemes", "description": "Recalled without web access and unsourced; every item is a lead to verify.", "evidence": [ { "scheme": "Molecular formula", "value_or_pattern": "C12H18", "note": "Specifies composition but does not distinguish iceane from its constitutional isomers." } ], "questions": [ { "id": "evidence-identifiers-q01", "text": "Which of these identifiers and schemes hold for the sense of iceane this model covers, and on what evidence?", "kind": "provenance" } ] }, { "id": "evidence-real-world-use", "name": "Real-world use", "description": "Recalled without web access and unsourced; every item is a lead to verify.", "evidence": [ "A target in synthetic organic chemistry and the study of cage hydrocarbon structures." ], "questions": [ { "id": "evidence-real-world-use-q01", "text": "Which of these real-world use hold for the sense of iceane this model covers, and on what evidence?", "kind": "provenance" } ] }, { "id": "evidence-neighbours", "name": "Neighbouring kinds and how to tell them apart", "description": "Recalled without web access and unsourced; every item is a lead to verify.", "evidence": [ { "name": "Adamantane", "difference": "Adamantane is a distinct cage hydrocarbon with formula C10H16 and a carbon framework related to the diamond lattice." }, { "name": "Ice", "difference": "Ice is solid water; iceane is a molecular hydrocarbon whose name refers to a structural resemblance." } ], "questions": [ { "id": "evidence-neighbours-q01", "text": "Which of these neighbouring kinds and how to tell them apart hold for the sense of iceane this model covers, and on what evidence?", "kind": "provenance" } ] } ] } ] } ] }, "openQuestions": [ "How should stereochemistry-explicit and stereochemistry-unspecified structure records for iceane be reconciled, and which representation should anchor this registry entry?", "Which primary experimental reports provide complete parent-iceane characterization and reference spectra suitable for authenticating new samples?", "What are the experimentally established melting, sublimation, decomposition and solubility data, including conditions and uncertainties?", "Which PubChem and EC identifiers, hazard classifications and exposure limits can be verified specifically for parent iceane, and where is information absent?", "Which demonstrated research uses and sample-quality requirements justify a use decision beyond recognizing iceane as a cage hydrocarbon?" ], "statistics": { "bundles": 6, "layers": 11, "findings": 14, "questions": 29 } }